Ab initio calculations of pure and Co+2-doped MgF2 crystals

It is known that MgF 2, which has a rutile structure, is characterized by high transparency in an extremely wide range of photon energies, from vacuum ultraviolet to infrared, and therefore has ...

Applied Sciences | Free Full-Text | Rutile in Amphibolite …

Rutile is an important ore mineral to meet the increasing demand of critical metal Ti in various sectors. Here we report a rare example of rutile deposits hosted within the Baishugang–Wujianfang amphibolite-facies metamorphic rocks in the East Qinling Orogen, central China. The rutiles are mostly located within or along the margins of …

Rutile: Mineral of Many Uses

Rutile is the preferred source of titanium ore (a metal whose strength, weight, and resistance to corrosion make it ideal for use in high-tech alloys). It has also been widely used in the production of glass, porcelain, and ceramics, as it is a valuable coloring agent. It can also be used to add color to steels and copper alloys, and is valued ...

3.22: Spinel, Perovskite, and Rutile Structures

The rutile structure is an important MX 2 (X = O, F) structure. It is a 6:3 structure, in which the cations are octahedrally coordinated by anions, and as such is intermediate in polarity between the CaF 2 (8:4) …

Rutilated Quartz: The Only Guide You Need

Rutilated quartz is a semi-precious stone highly praised for its unique patterns and glistening luster. Thus, it is one of the most sought stones for making statement jewelry. Rutile (titanium) is extremely strong but significantly light that is resistant to corrosion and does not react when exposed to the human body.

Rutile and its applications in earth sciences

Rutile has a wide range of applications in earth sciences. It is a major host mineral for Nb, Ta and other high field strength elements, which are widely used as a monitor of geochemical processes in the Earth's crust and mantle.

Mechanisms of Impurity Diffusion in Rutile

The results suggest that Sc, Cr, and Zr ions diffuse by an interstitialcy mechanism involving the simultaneous and cooperative migration of tetravalent interstitial …

Rutile: The titanium mineral in white paint and star …

Rutile is used as an ore of titanium, it is crushed into a white powder that is used as a pigment in paints, and it is processed for use in a multitude of products. Networks of …

Rutile Mineral Chemistry as a Guide to Provenance of Red

Rutile is the most stable and widely distributed TiO2 polymorph in rocks of low- to high-grade metamorphic facies and is also an accessory mineral in igneous rocks. Rutile is commonly available in modern to ancient placer mineral deposits in the coastal sediments. Mineral chemistry of rutile from red sediments and modern sands along …

Iron Removal and Recovery in the Titanium Dioxide

Ekstraksi rutile dilakukan dengan proses separasi magnetik, leaching dengan asam sulfat, penetralan dan kemudian proses sintering pada suhu 1000°C dengan holding time selama 7 jam.

[PDF] The superior lithium storage capabilities of ultra-fine rutile …

Crystallite Size Dependence of Lithium Intercalation in Nanocrystalline Rutile. N. Milne M. Skyllas-Kazacos V. Luca. Materials Science. 2009; An electrochemical investigation has been undertaken into the dependence of particle size on the mechanism of lithium intercalation in rutile. A thoroughly characterized suite of rutile nanoparticles ...

Rutile

Minerals: Rutile Rutile is the mineral name for natural crystals of titanium dioxide.It is a very hard (6-6.5 Moh) a: Minerals: Brookite A mineral form on titanium dioxide.: Minerals: Anatase A mineral form of titanium dioxide.: Glossary: Variegation Ceramic glaze variegation refers to its visual character. This is an overview of the various mechanisms …

Rutile

Rutile is a member of the tetragonal crystal system, it is a simple titanium dioxide TiO 2. Rutile is ordinarily prismatic, with distinct cleavage. Prisms may be striated vertically or furrowed. Prisms are rarely pyramidal. In igneous rocks, rutile can be granular or massive. Rutile is brittle, and tends to fracture along flat surfaces.

Reduced extrinsic recombination process in anatase and rutile …

Although the effective density of states of anatase (N C,anatase ~ 7.8 × 10 20 cm −3) 36 is larger than that of rutile (N C,rutile ~ 2.5 × 10 19 cm −3) 37, the slope of anatase (0.87 k B T/q) is more gradual compared with that of rutile (1.05 k B T/q). Considering that trap-assisted recombination is minimized due to epitaxy growth, the ...

Effect of Doping on Rutile TiO

Transition-metal-(TM-)doped TiO 2 has been considered as promising electrode material for the oxygen evolution reaction (OER). OER activity is expected to depend on the coordination of the surface atoms. In this study, we theoretically investigate the stability of low-index surfaces of TM-doped rutile, (110), (100), (101) and (001), with …

Precipitation of rutile and ilmenite needles in garnet: …

Connecticut rocks. (c) "Ghost" of earlier euhedral garnet outlined by rutile needles and microplates [58A-2]. Part (d) shows area enclosed by dashed rectangle. (d) Close-up of garnet in part c. Rutile inclusions become more abundant as the outer margin of the needle-rich zone is approached; most bright dots are rutile plates.

Rutile's fiery brilliance | Nature Geoscience

Rutile is the most thermodynamically stable form of titanium dioxide — TiO 2 — under most geologic conditions, and typically occurs as an accessory mineral in …

13.4.2: Pauling's Second Rule

13.4.2.1 Isodesmic, Anisodesmic, and Mesodesmic Crystals; Figure 13.17: Atoms in sylvite. Pauling's second rule, sometimes called the Electrostatic Valency Principle, says that we can calculate the strength of a bond (its …

Preparation and characterization of visible light sensitive …

As a result, Mordant/Rutile, N 3 /Rutile, CoPcTs/Rutile, and Pt/Rutile were obtained. Again, to study the role of platinum, dye precursors which were sensitive to light were loaded onto Pt/ TiO 2 (i.e., amount of platinum is one percent) and, hence, N 3 /Pt/TiO 2, Mordant/Pt/TiO 2, and CoPcTs/Pt/TiO 2 were obtained. Details of these sample ...

Crystalline phase regulation of anatase–rutile TiO2 for …

and rutile contents to further study the photocatalytic perfor-mance of biphasic TiO 2. This work aims to promote the photodegradation of organic pollutants by synthesizing a novel kind of spindle-like biphasic TiO 2 nanorods via hydrothermal-calcination route. The anatase and rutile contents in biphasic TiO 2 were adjusted by control-

Rutile Mineral Chemistry as a Guide to Provenance …

Keywords. Rutile is the most stable and widely distributed TiO2 polymorph in rocks of low- to high-grade metamorphic facies and is also an accessory mineral in …

Rutile

Rutile is a natural accessory mineral in metamorphic rocks such as gneiss, schist, and eclogite. Rutile crystals with a good shape can be found in pegmatite and skarn. Rutile and many other metallic ore minerals are mined together in sedimentary deposits called "heavy mineral sands." The weathering of igneous and metamorphic rocks that …

Improved light-induced cell detachment on rutile TiO

The phase compositions of Rutile-N and Rutile-500 were further explored by Raman spectroscopy (Fig. 5). The four peaks appear at 103, 237, 435 and 601 cm−1 on the Raman spectrum of Rutile-N, ascribed to B1g, second-order scattering (SOS), Eg and A1g modes of rutile TiO2 [38,39]. Similar to Rutile-N, four peaks located at 126, 235, 441 …

Ordered macroporous rutile titanium dioxide by …

300 nm in a rutile titania matrix. These differ from the air sphere/titania materials reported elsewhere in that the matrix is the high-index rutile phase of titania (n 2.9) as opposed to the low-index anatase phase (n 2.4). We make these materials by a sol-gel process with oil-in-formamide emulsions as templates. The emulsion droplets are

Rutile Structure 루틸 구조

Tantalum/nitrogen codoped titanium dioxide (TiO2:Ta,N) having a rutile structure has recently been reported to be a good photocatalyst for visible-light water oxidation. [17] These show similar chemistry as well as the same rutile structure, even when varying the relative oxygen flow-rate ratio (fO2) during deposition over a wide range. [18]

Effect of nitrogen doping on anatase–rutile phase …

N–TiO 2 nanoparticles were prepared by hydrolysis of TiCl 4 and characterized by means of XPS, SEM, XRD, TG-DSC and UV–vis DRS. The nitrogen was doped into TiO 2 lattice successfully, and the temperature of anatase phase transforming to rutile phase was found to be increased by N-doping. By comparison of the crystal …

Hydrogen Reduced Rutile Titanium Dioxide Photocatalyst

Highly efficient rutile photocatalyst is easily fabricated from P25 by H 2 reduction treatment at 700°C for 2 h [ 18 ]. The H 2 -reduced rutile TiO 2 outperforms anatase-rich TiO 2 because of the wider absorption range caused by its bandgap of rutile (3.0 eV) smaller than that of anatase (3.2 eV).

How To Use Rutile In Your Pottery – MommyLikeWhoa

Rutile is a mineral that is used as a glaze in pottery. It is a source of titanium dioxide, which is a white pigment that is used to produce a wide range of colors in glazes. Rutile is also used as a flux, which helps to lower the melting point of the glaze and improve its flow. The rutile used to make potassium titanate is a feedstock in ...

Acidic Peptizing Agent Effect on Anatase-Rutile Ratio and

The results confirmed that the TiO2 sample peptized using nitric acid (with rutile and anatase phases in 3:1 ratio) offered the highest activity for degradation of organic dyes, although, TiO2 ...

B. Generalized Proc ess Description

production. The developme nt of processes to produce synthetic rutile was necessitated by the small quantity of economic reserves of natural rutile worldwide.2 Thus, despite the fact that the U.S. has large reserves of ilmenit e, the majority of sponge produced is manufactured from imported rutile and syntheti c rutile, primarily from Australia and

Rutile Meaning, Benefits, and Uses

Rutile is perhaps most noted for its metaphysical properties. It has many uses and applications, including the following: yoga, relax, exercise, therapy. Manifestation. Rutile is said to help quicken manifestation. If there are deep desires you wanted to be fulfilled, rutile can help those wishes come true sooner.

Nanomaterials | Free Full-Text | The Anatase-to-Rutile Phase …

An array of highly oriented anatase nanoparticles was successfully prepared from NH4TiOF3 with the assistance of polyetheleneglycol-400 at 450 °C. The study showed the stability of obtained layered TiO2-anatase close to 1200 °C. This research confirmed for the first time that the transition of mesocrystalline anatase to the rutile phase occurs …

A recipe for the use of rutile in sedimentary …

Sedimentary provenance analysis aims at qualitative and quantitative reconstruction of the lithology of source rocks of clastic sediments and, in a wider sense, …

Photocatalytic degradation of methylene blue by flowerlike rutile …

2.3 Characterisations. For X-ray diffraction (XRD), PANalytical X'Pert Powder at 2θ angles from 20° to 80° was used to investigate the crystal structure of the TiO 2 films. Raman spectroscopy (Xplora plus model BX41TF) was used to confirm the structural property of the rutile-phase TiO 2 film. Scanning electron microscopy (SEM; JEOL JSM …

UPb LA-(MC)-ICP-MS dating of rutile: New reference …

1. Introduction. Rutile, the most common polymorph of TiO 2, is a widely distributed accessory mineral in medium- to high-grade metamorphic and some igneous, chiefly plutonic, rocks.Due to its chemical and physical stability during the sedimentary cycle, rutile is commonly found in the heavy mineral suite of sedimentary rocks and can …

Minerals | Free Full-Text | Rutile and Chlorite …

The chemical composition of rutile has been used as an indicator in magmatic and metamorphic-related diagenetic systems, but rarely in porphyry-style ore systems. The Tuwu deposit (557 Mt at 0.58% …

Green sol–gel route for selective growth of 1D rutile …

Effects of TFA on the structure and morphology of N–TiO 2 were studied by varying concentration of TFA between 1–10% by volume. Structural characterization using XRD confirmed formation of a specific rutile phase with slight crystal disorder with N-doped TiO 2 samples. FESEM and HRTEM analysis showed formation of 1D rice grain shaped N–TiO

Rutile Properties, Uses, Formation » Geology Science